The conversion of acyl silanes into chiral secondary alcohols
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 89-90
- https://doi.org/10.1039/c39890000089
Abstract
Chiral secondary carbinols are prepared in high enantiomeric excess by a new process involving the reduction of acyl silanes and utilising a thermal rearrangement of α-acetoxy silanes.Keywords
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