Higher Approximations for the Transport Properties of Binary Gas Mixtures. I. General Formulas
- 1 July 1957
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 27 (1) , 75-84
- https://doi.org/10.1063/1.1743721
Abstract
Higher approximations for the transport properties of binary gas mixtures are derived: (1) by the method of Chapman and Cowling; (2) by an extension of a method due to Kihara. Particular attention is paid to diffusion and thermal diffusion because of their importance in obtaining information on the forces between unlike molecules. The results can be used to test the convergence and accuracy of the theoretical formulas for various molecular models, and to supply higher correction terms if needed.Keywords
This publication has 9 references indexed in Scilit:
- Thermal Diffusion in Krypton and ArgonThe Journal of Chemical Physics, 1956
- Combination Rules for Potential Parameters of Unlike Molecules on Exp-Six ModelThe Journal of Chemical Physics, 1956
- Infrared Spectra of Some Deuterated SilanesThe Journal of Chemical Physics, 1956
- Forces between Unlike Molecules and the Properties of Gaseous MixturesThe Journal of Chemical Physics, 1955
- The Intermolecular Potentials of Helium and HydrogenThe Journal of Chemical Physics, 1954
- Transport Properties of Gases Obeying a Modified Buckingham (Exp-Six) PotentialThe Journal of Chemical Physics, 1954
- Virial Coefficients and Models of Molecules in GasesReviews of Modern Physics, 1953
- Thermal Diffusion of Gas Mixtures and Forces between Unlike MoleculesProceedings of the Physical Society. Section A, 1953
- The Transport Properties of Gases and Gaseous Mixtures. II.Chemical Reviews, 1949