Reaction of cycloheptatriene with ruthenium carbonyl: X-ray crystallographic determination of the molecular structure of Ru3(CO)6(C7H7)(C7H9)
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 726-727
- https://doi.org/10.1039/c39730000726
Abstract
Cycloheptatriene reacts with dodecacarbonyl-triruthenium to give inter alia a fluxional complex Ru3(CO)6(C7H7)(C7H9)(I), an X-ray diffraction study of which reveals that the C7H7 ring bridges two of the ruthenium atoms whereas the C7H9 ring is attached to the remaining metal atom as a cycloheptadienyl ligand.Keywords
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