Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 278-280
- https://doi.org/10.1039/c39880000278
Abstract
The new 16-electron ruthenium compounds (η5-C5Me5)Ru(L)Cl [(1), L = PPri 3; (2), L = PCy3](Cy = cyclohexyl) were prepared from [(η5-C5Me5)RuCl]4 and PPri 3 or PCy3, respectively, and the X-ray crystal structure of (1) has been determined; reactions of the title compounds with CO, C2H4, pyridine, and PhSiH3 are described.Keywords
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