A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerene, Sc3N@C80
- 29 December 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (4) , 524-525
- https://doi.org/10.1021/ja0171005
Abstract
The reaction of Sc3[email protected]80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3[email protected]80 cage.Keywords
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