Catalytic formation of aziridines from imines and diazoacetate
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1401-1402
- https://doi.org/10.1039/c39950001401
Abstract
A catalytic method for the preparation of aziridines from imines and diazoacetate is developed using copper complexes as catalyst; the synthetic, diastereo- and enantio-selective scope of the reaction are presented.Keywords
This publication has 16 references indexed in Scilit:
- On the reaction of chiral sulfinimines with sulfur ylides: a novel route to the asymmetric aziridinationTetrahedron Letters, 1995
- Development of the Copper-Catalyzed Olefin Aziridination ReactionJournal of the American Chemical Society, 1994
- Chiral Aziridines—Their Synthesis and Use in Stereoselective TransformationsAngewandte Chemie International Edition in English, 1994
- Epoxidation and hydroxylationPublished by Wiley ,1993
- Studies on N-metallo imines: synthesis of N-unsubstituted aziridines from N-trimethylsilyl imine and lithium enolates of α-halo esters.Tetrahedron Letters, 1991
- A convenient synthesis of optically active 1H-aziridine-2-carboxylic acids (esters)Tetrahedron Letters, 1989
- .alpha.,.beta.-Epoxy sulfoxides as useful intermediates in organic synthesis. 22. Stereospecific desulfinylation of sulfinylaziridines with alkylmetals: a novel synthesis including asymmetric synthesis of (Z)-N-arylaziridines and some mechanistic studiesThe Journal of Organic Chemistry, 1989
- Transition-metal-catalyzed epoxidationsChemical Reviews, 1989
- An aziridine route to chiral β-lactams a novel entry to (+)-thienamycinTetrahedron Letters, 1987
- Cyclodehydration of N- and C-substituted .beta.-amino alcohols to the corresponding aziridines with diethoxytriphenylphosphoraneThe Journal of Organic Chemistry, 1986