Laser-induced electronic transitions in a molecular beam: The dipole moment of d 3Δi i v=4 carbon monoxide
- 1 December 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (11) , 4952-4964
- https://doi.org/10.1063/1.434678
Abstract
Measurement of the Stark effect in the CO transition a 3Πv=0→d 3Δiv=4 is made using a tunable dye laser as resonance radiation in a Rabi‐type molecular beam electric resonance spectrometer. The observed spectral linewidths are 4 MHz (FWHM). The electric dipole moment of CO d3Δiv=4 is 0.42±0.02 D. The sign of the moment is determined to be C−O+.Keywords
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