ENERGY LEVELS OF TRIARYLMETHYL CARBONIUM IONS
- 1 April 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (4) , 810-817
- https://doi.org/10.1139/v64-120
Abstract
The near ultraviolet and visible spectra of the various phenyl-, p-biphenyl methyl carbonium ions have been investigated and the polarization of the absorptions relative to the fluorescence band have been determined. An assignment of the transitions is made, using as a basis simple molecular orbital calculations and the expectations based on the structure representation. These are compared to the assignments made in earlier researches. The calculated intensities are found to agree favorably with the observed values.Keywords
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