Stereochemistry of bromofluorination of phenyl-substituted olefins
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 971-975
- https://doi.org/10.1039/p19760000971
Abstract
Bromofluorination of phenyl-substituted olefins, e.g. 1,1-diphenylethylenes, β-alkylstyrenes, and stilbene, with N-bromosuccinimide–hydrogen fluoride–pyridine in ether proceeds with Markovnikov-type regioselectivity. The reaction is sterospecific (anti) for trans- and nonstereospecific for cis-olefins.Keywords
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