EFFECT OF COMPLEXING ON THE HOMOGENEOUS CATALYTIC ACTIVATION OF HYDROGEN BY CUPRIC SALTS
- 1 April 1956
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 34 (4) , 554-562
- https://doi.org/10.1139/v56-076
Abstract
The effects of various organic and inorganic complex-forming reagents on the homogeneous catalytic activation of H2 by Cu++ in aqueous solution have been determined. The catalytic activities of the cupric complexes decrease in the order: butyrate, propionate > acetate > SO4− > Cl− > H2O (i.e. the uncomplexed Cu++ ion) > glycine, ethylenediamine. The mechanism of the activation process is discussed.Keywords
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