Investigation of the structure of trimethylsilylated secondary amides by 13C n.m.r. spectroscopy

1 January 1979

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1

p. 2478-2480
https://doi.org/10.1039/p19790002478

Abstract

¹³ C N. m. r. has been shown to be a further valuable tool for investigating the position of silylation in trimethylsilylated secondary amides. Whereas most lactams are N-silylated and 2-hydroxypyridines O-silylated, acetanilides exist as a mixture of isomers.

Keywords

STRUCTURE
SECONDARY
TRIMETHYLSILYLATED
AMIDES
13C
LACTAMS
ACETANILIDES
N.M.R
HYDROXYPYRIDINES
ISOMERS

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