Studies on Amino-hexoses. VII The N-Deacetylation of Methyl N-Acetyl α-d-Glucosaminide
- 1 April 1964
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 37 (4) , 468-470
- https://doi.org/10.1246/bcsj.37.468
Abstract
Methyl N-acetyl-α-d-glucosaminide has been found to be well N-deacetylated by hydrazine treatment. The methyl α-d-glucosaminide thus produced shows so much stability with regarded to hydrazine and to barium hydroxide that these reagents provide a convenient means of preparing anomerically-pure methyl d-glucosaminide and its hydrochloride. The free base of methyl α-d-glucosaminide has been obtained crystalline for the first time.This publication has 6 references indexed in Scilit:
- Separation of Methyl N-Acetyl-D-glucosaminide AnomersThe Journal of Biochemistry, 1963
- Hydrazinolysis of Acid Mucopolysaccharides*The Journal of Biochemistry, 1962
- Hydrazinolysis of Simple PolysaccharidesThe Tohoku Journal of Experimental Medicine, 1962
- Hydrazinolysis of mucopolysaccharidesBiochimica et Biophysica Acta, 1961
- Chondroitin Sulfate Modifications. II.1 Sulfated and N-Deacetylated PreparationsJournal of the American Chemical Society, 1960
- Studies on Amino-hexoses. IV. N-Deacylation with Hydrazine and Deamination with Nitrous Acid, a Clue to the Structure of AminopolysaccharidesBulletin of the Chemical Society of Japan, 1957