Formation et stabilité de complexes hydroxo–ammonio en solution aqueuse. I. Complexes de zinc
- 15 May 1968
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 46 (10) , 1707-1714
- https://doi.org/10.1139/v68-284
Abstract
A new method has been developed for the calculation of the formation constants of complexes in equilibrium with a precipitate in aqueous solution. This has been applied to the study of ammonio and ammonio–hydroxo complexes of zinc in the presence of the hydroxide. The curves of solubility vs. pH and pNH3 tot have been established by means of 65Zn at 25 °C and ionic strength 1.0 with NaClO4.Keywords
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