The Crystal Structure of Bis(2,2′-bipyridyl)palladium(II) Picrate [Pd(bpy)2](pic)2. A Novel “Bow” Distortion
- 1 June 1986
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (6) , 2013-2014
- https://doi.org/10.1246/bcsj.59.2013
Abstract
The title complex crystallized in the triclinic space group P\barl with a=8.228(2), b=13.493(2), c=7.753(1)Å; α=96.96(1), β=106.16(1), γ=99.99(1)°; Z=1. The structure was solved by the heavy-atom method and refined by the block-diagonal least-squares method to R=0.0366. It is found that picrate ions above and below the [pd(bpy)2]2+cation stack with the bpy molecules and that this stacking leads to a novel bow distortion of the cation.Keywords
This publication has 4 references indexed in Scilit:
- Structure of bis(1,10-phenanthroline)platinum(II) dichloride trihydrateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1980
- The 1:3 radical salt bis(2,2'-dipyridyl)platinum(II)–7,7,8,8-tetracyanoquinodimethane, [Pt(dipy)2]2+[TCNQ]3 2−Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1978
- Dimerization of 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anions via σ-bond formation: crystal structure and EPR properties of bis(dipyridyl)platinum(II)–TCNQ, [Pt(2,2'-dipy)2 2+(TCNQ)2 2−]Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1977
- The steric effect in bis(2,2'-bipyridyl) and bis(1,10-phenanthroline) metal compoundsCoordination Chemistry Reviews, 1971