Stereoselective synthesis of phosphonothionates from phosphonate analogues: basic hydrolysis of chiral phosphonothionates to a racemic product
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 7,p. 366-367
- https://doi.org/10.1039/c29710000366
Abstract
Chiral phosphonates reacted with P4S10 to give their thionoanalogues with predominant (if not complete) retention of configuration; basic hydrolysis of the phosphonothionates gave completely recemic products.Keywords
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