Photochemical studies of unimolecular processes I. The photoisomerization of cycloheptatriene and cycloheptatriene-d 8
- 31 March 1970
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 316 (1524) , 123-130
- https://doi.org/10.1098/rspa.1970.0069
Abstract
The photochemical isomerization of cyclo [1.3.5] heptatriene to toluene was studied at seven wavelengths between 228.8 and 313.0 nm. It was shown to occur via a vibrationally excited ground state molecule, the isomerization being quenched by added gases (the parent molecule, toluene, SF$_{6}$, CO$_{2}$, He) according to the Stern-Volmer law. The perdeuteriated compound was also studied.Keywords
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