A practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols using kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the sharpless process
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1323-1325
- https://doi.org/10.1039/c39860001323
Abstract
Kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the Sharpless process, which proceeds with very large rate differences for the two isomers, combined with the reactivity of epoxysilyl compounds affords a practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols.Keywords
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