Selective Cleavage of Dimethylhydrazones to the Carbonyl Compounds Using Silica Gel and its Application in the Synthesis of (Z)-9-Tetradecenyl Acetate
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (09) , 694-698
- https://doi.org/10.1055/s-1989-27363
Abstract
A new method for the selective hydrolytic cleavage of dimethylhy- drazones consists of treatment of the hydrazones with silica gel (pH 6.80) in wet tetrahydrofuran. Utilizing this method as one of the key steps, (Z)-9-tetradecenyl acetate, the pheromone of Spodoptera frugiperda, was synthesized.Keywords
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