Déplacement induit par un lanthanide en résonance magnétique nucléaire. Une application à un problème stéréochimique

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Abstract
Shifts induced by tris(dipivalomethanato) praseodymium (III) have been applied to the determination of the stereochemistry of cis and trans 4-tert-butyl 1,2,2-trimethyl cyclohexanols. Observed shifts were at higher field than tetramethylsilane and a linear relationship has been established between the induced shifts and the cube of reciprocal distance metal-hydrogen.

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