Dehydrochlorination of chlorodihydridocarbonylbis(triphenylphosphine)Ir(III) in the presence of strong bases
- 15 April 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (8) , 1431-1433
- https://doi.org/10.1139/v69-234
Abstract
The dehydrochlorination of dihydridochlorocarbonylbis(triphenylphosphine)iridium(III) by organic and inorganic bases is described. The manner in which this reaction provides a formal link between the homolytic activation of hydrogen at a single metal center and the heterolytic activation of hydrogen is discussed.Keywords
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