Efficient Addition of Allylsilanes to α,β-Enones Using Catalytic Indium and Trimethylsilyl Chloride
- 19 August 2003
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2003 (14) , 2189-2193
- https://doi.org/10.1055/s-2003-41017
Abstract
α,β-Enones undergo an efficient Hosomi-Sakurai reaction with allyltrimethylsilane, in which a catalytic amount of indium is used in the presence of trimethylsilyl chloride as an activator under mild conditions to produce the conjugate addition products in good yields.Keywords
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