Crystal Spectra of Hexaurea Complexes. III. Optical and Magnetic Properties of Crystals Containing the Hexaurea Vanadium (III) Ion

1 March 1969

journal article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 50 (5) , 1957-1962
https://doi.org/10.1063/1.1671314

Abstract

Low-temperature polarized crystal spectra of the [V(urea)6]3+ ion are presented and discussed. In many ways they closely resemble those seen in V3+/Al2O3. The ground-state splitting of A23 has been established by both optical and magnetic means and is reported as 6.0 ± 0.5 cm−1. The source of spectral intensity is almost entirely due to the influence of the static, odd crystal field.

Keywords

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