Dynamics of reaction of ion pairs in aqueous solution: racemization of the chiral ion pair intermediate of solvolysis of (S)‐1‐(4‐methylphenyl)ethylpentafluorobenzoate
- 6 August 2003
- journal article
- Published by Wiley in Journal of Physical Organic Chemistry
- Vol. 16 (8) , 484-490
- https://doi.org/10.1002/poc.611
Abstract
No abstract availableKeywords
This publication has 19 references indexed in Scilit:
- Enantiomer-Specific Oxygen Exchange Reactions. 2. Acid-Catalyzed Water Exchange with 1-Phenyl-1-alkanolsJournal of the American Chemical Society, 1994
- On the importance of carbocation intermediates in bimolecular nucleophilic substitution reactions in aqueous solutionJournal of the American Chemical Society, 1993
- Experiments and calculations for determination of the stabilities of benzyl, benzhydryl, and fluorenyl carbocations: antiaromaticity revisitedJournal of the American Chemical Society, 1992
- On the importance of reactions of carbocation ion pairs in water: common ion inhibition of solvolysis of 1-(4-methoxyphenyl)-2,2,2-trifluoroethyl bromide and trapping of an ion-pair intermediate by solventThe Journal of Organic Chemistry, 1992
- Effect of .beta.-fluorine substituents on the rate and equilibrium constants for the reactions of .alpha.-substituted 4-methoxybenzyl carbocations and on the reactivity of a simple quinone methideJournal of the American Chemical Society, 1990
- How does a reaction change its mechanism? General base catalysis of the addition of alcohols to 1-phenylethyl carbocationsJournal of the American Chemical Society, 1986
- General base catalysis of the addition of hydroxylic reagents to unstable carbocations and its disappearanceJournal of the American Chemical Society, 1984
- Sylvolytic Substitution in Simple Alkyl SystemsPublished by Wiley ,1974
- Electrophilic substitution at saturated carbon. L. Isoinversion without an available conducted tour pathway for proton transferJournal of the American Chemical Society, 1972
- Ion-pair return associated with solvolysis of .alpha.-p-anisylethyl and .alpha.-phenylethyl p-nitrobenzoatesJournal of the American Chemical Society, 1970