Julia–Colonna asymmetric epoxidation of furyl styryl ketone as a route to intermediates to naturally-occurring styryl lactones
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 103-106
- https://doi.org/10.1039/a808436j
Abstract
The enone 1 was oxidized stereoselectively using urea-hydrogen peroxide with polyeucine as the catalyst to give the epoxide 2 which was used to make (+)-goniotriol 7, (+)-goniofufurone 8, (+)-8-acetylgonitriol 9 and gonio-pypyrone 10.Keywords
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