Coupling Alkylation of (E)-α-Selanylvinylic Zirconium Compounds to Give Trisubstituted Alkenes
- 1 April 1999
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 29 (8) , 1421-1427
- https://doi.org/10.1080/00397919908086120
Abstract
Hydrozirconation of internal acetylenic selenides afforded 1.1-bimetalloalkenes, (E)-α-selanylvinylzirconium, which can undergo sequential cross coupling reaction to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereoselectively.Keywords
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