Co-ordination chemistry at a triply bridging site of [Pd3(µ3-CO)(µ-Ph2PCH2PPh2)3]2+: the structure of the chloride adduct
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 536-537
- https://doi.org/10.1039/c39850000536
Abstract
The selective attachment of halide ions to a triply bridging site in the complex cation [Pd3(µ3-CO)(µ-dppm)3]2+(dppm = Ph2PCH2PPh2) has been established and the structure of the chloride adduct determined; the chloride ligand is very weakly bound to the Pd3 unit and is shielded by a ring of phenyl groups from the dppm ligands.Keywords
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