Synthesis and chiroptical properties of optically active layer-block dendrimers
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1185-1186
- https://doi.org/10.1039/cc9960001185
Abstract
The syntheses of two different homochiral, layered-block dendrimers 1 and 2 are reported; the chiral units used in the construction of these two first-generation dendrimers are derivatives of (D)- and (L)-tartaric acid; for these low generation dendrimers, the optical rotation strength of the (D)-tartaric derived chiron cancels out that of its antipodal (L)-tartaric derived chiral unit.Keywords
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