Cu2+-promoted Hydrolysis of cyanomethyl-substituted tetra-azamacrocycles
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 603-604
- https://doi.org/10.1039/c39810000603
Abstract
The fast Cu2+-promoted hydrolysis of the two macrocyclic nitriles (3) and (4) is due to the proximity of the reactants allowing an intramolecular nucleophilic attack of the co-ordinated OH– on the cyano-group to take place.Keywords
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