First Enantioselective Total Synthesis and Absolute Configurations of 4,5-Dioxo-seco-γ-eudesmol and 5β,11-Dihydroxyiphionan-4-one, Two Aglycones of Naturally Occurring Sesquiterpenes with New Skeletons
- 31 December 2001
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2001 (01) , 0037-0039
- https://doi.org/10.1055/s-2001-9742
Abstract
A facile synthetic route to two new carbon skeleton sesquiterpenes 4,5-dioxo-seco-γ-eudesmol and 5β,11-dihydroxyiphionan-4-one from (+)-dihydrocarvone has been described. The configuration of the 5β,11-dihydroxyiphionan-4-one was confirmed by stereospecific synthesis.Keywords
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