PSEUDOTETRAHEDRAL COBALT(II) COMPLEXES OF C3vand CsSYMMETRIES
- 1 July 1984
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 13 (3) , 197-206
- https://doi.org/10.1080/00958978408073868
Abstract
New complexes of the general types HCoX3 ·nL and HCo Y2X·nL (X=Br, I; Y=Cl, Br, I; L=diethyl ether, pyridine, aniline; n=1, 2, 3 and 4) have been prepared and characterized by elemental analyses, molar conductance measurements, magnetic measurements, spectral (UV, visible, IR and far-IR) data and X-ray powder patterns. All the magnetic and spectroscopic results indicate that pseudotetrahedral [CoX3L]− and [CoY2XL]− anions are present in the solid pyridine and aniline complexes. The data for the solid compounds are compatible with, and lend support to, outer spheres comprising (N[sbnd]H[sbnd]N)+ groups.Keywords
This publication has 31 references indexed in Scilit:
- Etherate, pyridine and aniline compounds of mixed complex halogen acids of indium (III)Inorganic and Nuclear Chemistry Letters, 1980
- Etherate, pyridine, and aniline compounds of the complex tri- and tetra-iodoacids of Zn(II) and Cd(II)Monatshefte für Chemie / Chemical Monthly, 1980
- Electronic, infrared and far-infrared study on pseudotetrahedral cobalt(II) zwitterion complexesInorganica Chimica Acta, 1978
- Complex compounds of bromoacids of tin(II) with aniline and pyridineInorganic and Nuclear Chemistry Letters, 1978
- Structures of the Intermediate Complexes in Friedel‐Crafts AcylationsAngewandte Chemie International Edition in English, 1974
- Applications of ion-selective electrodesAnalytica Chimica Acta, 1971
- Pyridinetrihalogenometallate anions, pyMX3–, of cobalt(II), nickel(II), and zinc(II)J. Chem. Soc. A, 1968
- The far infrared spectra of ligand-metal-halide complexes of pseudotetrahedral symmetrySpectrochimica Acta Part A: Molecular Spectroscopy, 1967
- Dimethylsulfoxide as Solvent for Acidimetric Determination of Ammonium and Substituted Ammonium Ions.Analytical Chemistry, 1964
- Magnetic Investigations of Spin-free Cobaltous Complexes. VI.1 Complexes Containing Phosphines and the Position of Phosphines in the Spectrochemical SeriesJournal of the American Chemical Society, 1961