Synthesis and Spectral Studies on Metal Complexes of 2-Alkylthio-5-Mercapto-1,3,4-Thiadiazoles
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 16 (9) , 1289-1304
- https://doi.org/10.1080/00945718608071401
Abstract
Complexes of the type ML2, where M = Ni(II), Pd(II) or Cd(II) and HL = 2-methylthio- or isopropylthio- or butylthio-5-mercapto-1,3,4-thiadiazole, have been synthesized and characterized by elemental analyses, i.r. and 13 C NMR spectral and magnetic susceptibility data. The ligands exist predominantly in the thione form in the solid state and in DMSO solution. Both thione-thiol forms are, however, present in concentrated chloroform solutions. The i.r. spectral data show involvement of both N and S− in bonding with metal ions.Keywords
This publication has 16 references indexed in Scilit:
- 1,3,4-ThiadiazolesPublished by Elsevier ,1984
- Tin (IV) tetrahalide complexes of 2,5-disubstituted 1,3,4-thiadiazolesSpectrochimica Acta Part A: Molecular Spectroscopy, 1980
- Spectral and magnetic studies on the complexes of 2,5-dimercapto-1,3,4-thiadiazole (bismuthiol I) with Co(II), Ni(II), Zn(II), Cd(II) and Hg(II)Journal of Inorganic and Nuclear Chemistry, 1977
- Complexing behaviour of 1,3,4-thiadiazole-2-thiol-5-amino—I: Complexes of Fe(II), Co(II), Ru(III), Ru(II), Rh(III), Pd(IV), Ir(III) and Pt(IV)Journal of Inorganic and Nuclear Chemistry, 1975
- 1, 3, 4‐Thiadiazole‐2, 5‐dithiol as a Complexing Agent II. Complexes of NiII, RhI, PdII, PtII, AuIII, and CuIIZeitschrift für anorganische und allgemeine Chemie, 1975
- Thioamide bands and nature of bonding—IIJournal of Inorganic and Nuclear Chemistry, 1974
- The C=S stretching frequency and the “-N-C=S bands” in the infraredSpectrochimica Acta, 1962
- Cyclizations of Thiocarbohydrazide and its Mono-hydrazones. Part III. Reactions with Carbon Disulphide in Pyridine.Acta Chemica Scandinavica, 1961
- ABSORPTION SPECTRA OF 2,5-DIMERCAPTO-1,3,4-THIADIAZOLE AND ITS METHYL DERIVATIVESCanadian Journal of Chemistry, 1960
- S-ALKYL-2,5-DIMERCAPTO-1,3,4-THIADIAZOLESCanadian Journal of Botany, 1958