A CONVENIENT METHOD FOR THE PREPARATION OF OLEFINS BY REDUCTIVE DEMETHOXYLATION OF ALLYL METHYL ETHERS USING TiCl4–LiAlH4

5 July 1976

journal article
research article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 5 (7) , 737-738
https://doi.org/10.1246/cl.1976.737

Abstract

The reductive demethoxylation of allyl methyl ethers using TiCl₄–LiAlH₄ afforded various olefins in good yields accompanied with double bond migration.

Keywords

OLEFINS
CONVENIENT METHOD
METHYL ETHERS
USING TICL4
REDUCTIVE DEMETHOXYLATION
ALLYL METHYL
LIALH4

This publication has 2 references indexed in Scilit:

New method for the reductive coupling of carbonyls to olefins. Synthesis of .beta.-carotene
Journal of the American Chemical Society, 1974
The mechanism of mixed hydride reductions. Effects of reagent composition, nature of halogen, and solvating ligand on the mechanism of epoxide reduction
Journal of the American Chemical Society, 1968