Laser photofragment study of ethyl chloride cation at 5145 Å
- 15 May 1982
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 76 (10) , 5185-5186
- https://doi.org/10.1063/1.442829
Abstract
We present the product kinetic energy distribution for the photodissociation of the ethyl chloride cation at 5145 Å. The energy partitioning is consistent with a direct dissociation mechanism in which a combination of recoil effects and FrancknCondon effects dispose 85% of the available energy into fragment internal degrees of freedom. (AIP)Keywords
This publication has 8 references indexed in Scilit:
- Laser photofragment spectroscopy of the 1,3-butadiene cation at 5145 ÅThe Journal of Chemical Physics, 1981
- Laser-induced photodissociation of chloroethane molecular ions in the gas phaseThe Journal of Chemical Physics, 1979
- Photofragmentation of CH3Cl+ at 366 nmThe Journal of Chemical Physics, 1978
- Photodissociation of CH3I+ and CD3I+The Journal of Chemical Physics, 1977
- Energy partitioning by mass spectrometry: Chloroalkanes and chloroalkenesThe Journal of Chemical Physics, 1974
- Photoelectron Spectra and Orbital Structures of Higher Alkyl Chlorides, Bromides, and IodidesBulletin of the Chemical Society of Japan, 1973
- Triatomic Photofragment Spectra. I. Energy Partitioning in NO2 PhotodissociationThe Journal of Chemical Physics, 1972
- Reformulation of the quasiequilibrium theory of ionic fragmentationThe Journal of Physical Chemistry, 1971