Anisotropy of the Line Tension and Bulk Elasticity in Two-Dimensional Drops of a Mesophase
- 27 March 1995
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 74 (13) , 2495-2498
- https://doi.org/10.1103/physrevlett.74.2495
Abstract
Using Brewster angle microscopy to study Langmuir monolayers of fatty acids at the air-water interface, we have observed a boojum pattern in two-dimensional drops of a tilted liquid condensed phase. In a boojum, the in-plane molecular orientation turns continuously and points with the same molecular orientation are located on straight lines, crossing at a defect point expelled from the drop. We have observed a distortion of the drops in the neighborhood of these points. We have studied the distortion of the drops and the distance of the defect point to the drop boundary, and deduced several ratios between elastic constants, anisotropic line tension, and elastic constants of the medium.Keywords
This publication has 16 references indexed in Scilit:
- Stars, stripes and shells in monolayers: simulation of the molecular arrangement in Schlieren structuresThin Solid Films, 1994
- Tilt stripe textures in Langmuir monolayers of fatty acidsPhysica A: Statistical Mechanics and its Applications, 1994
- Fluctuations of a defect line of molecular orientation in a monolayerPhysical Review E, 1994
- Splay stripe textures in Langmuir monolayersThe Journal of Physical Chemistry, 1993
- Phase transitions in Gibbs films: Star textural defects in tilted mesophasesThe Journal of Chemical Physics, 1993
- Direct observation of domain structure in condensed monolayer phasesPhysical Review Letters, 1991
- A monolayer phase miscibility comparison of long-chain fatty acids and their ethyl estersThe Journal of Physical Chemistry, 1991
- Direct visualization of monolayers at the air-water interface by Brewster angle microscopyThe Journal of Physical Chemistry, 1991
- Microscope at the Brewster angle: Direct observation of first-order phase transitions in monolayersReview of Scientific Instruments, 1991
- Textures in a chiral smectic liquid-crystal filmPhysical Review A, 1986