Fluorescence excitation spectrum of the Si–Ar van der Waals complex
- 1 March 1990
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 92 (5) , 2828-2836
- https://doi.org/10.1063/1.457929
Abstract
We report here the fluorescence excitations spectrum of the Si–Ar van der Waals complex in the region of the (3p4s)3P–(3p2)3P atomic transition. Long progressions are observed, which have been assigned to a Π–Σ transition. The potential curves derived from the analysis of these progressions are discussed in terms of effects of spin–orbit coupling on van der Waals interactions.Keywords
This publication has 10 references indexed in Scilit:
- Interatomic potentials for van der Waals complexes of group 13 metal atoms: AlAr, AlKr, and AlXeThe Journal of Chemical Physics, 1989
- Fluorescence excitation spectra of the XeCl(B, C) states in a supersonic jetChemical Physics Letters, 1989
- Spectroscopic characterization of the lowest singlet states of CdNe, CdAr, and CdKrThe Journal of Chemical Physics, 1989
- Interatomic potentials for van der Waals complexes of group 13 metal atoms: InAr, InKr, and InXeThe Journal of Chemical Physics, 1989
- Resonant photoionization spectroscopy of refractory metal-rare gas complexes: AlArChemical Physics Letters, 1987
- The structure of several electronic states of the Hg–Ar complex as determined by laser double resonance in a supersonic jetThe Journal of Chemical Physics, 1986
- The energy of the lowest triplet state of gas phase benzeneThe Journal of Chemical Physics, 1984
- Electronic spectra of van der Waals molecules HgNe, HgAr, and HgKr in a supersonic jetThe Journal of Chemical Physics, 1984
- Production of triplets and cold radicals with a pulsed electric discharge in a pulsed supersonic bea]tlChemical Physics Letters, 1984
- The dispersed fluorescence spectrum of NaAr: Ground and excited state potential curvesThe Journal of Chemical Physics, 1979