Enantioselective conjugate addition of thiols to enones and enals catalyzed by chiral N-oxide–cadmium complex
- 1 January 2000
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1851-1852
- https://doi.org/10.1039/b005994n
Abstract
A novel method of enantioselective conjugate addition of thiols to enones and enals produces sulfides with enantioselectivities up to 78% ee, employing a cadmium complex of (S)-3,3′-dimethyl-2,2′-biquinoline N,N′-dioxide 1 as a catalyst.Keywords
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