Magnetic-field-induced quadrupole splitting
- 1 January 1968
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 14 (5) , 457-464
- https://doi.org/10.1080/00268976800100571
Abstract
The general expression for the magnetic-field-induced quadrupole splitting is derived for dn transition metal ions in a crystal field of octahedral symmetry. The effective magnetic field may arise from either an applied field or a molecular field. Bonding effects are also treated. The temperature dependence of the quadrupole splitting ΔEQ induced by an applied magnetic field is calculated for 57Fe high-spin ferrous and low-spin ferric compounds where the ions are in crystal fields of octahedral symmetry.Keywords
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