Crystal structure of Bis(2,2':6',2''-terpyridyl)cobalt(III) chloride
- 1 January 1983
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 36 (8) , 1563-1571
- https://doi.org/10.1071/ch9831563
Abstract
The crystal structure of the title compound [CO(C15H11N3)2]Cl3 has been determined by single crystal X-ray diffraction methods at 295 K and refined by least-squares methods to a residual of 0.069 for 2953 'observed' reflections. Crystals are triclinic, PI, a 9.018(4), b 11.751(4), c 18.085(6)�, α 9O.82(6), β 9O.66(7), γ 90.79(7)�, Z 2. The determination establishes for the first time metal-nitrogen distances in the bis(terpyridyl)cobalt(III) species; (Co-N)(central, distal) are 1.86, 1.93 �. The precision of the determination is adversely affected by widespread solvent/anion disorder.Keywords
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