Redox-catalysed isomerisation of manganese carbonyl derivatives
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 992-993
- https://doi.org/10.1039/c39860000992
Abstract
The isomerisation of the manganese(I) complex trans-[MnBr(CO)2{P(OPh)3}(dppm)][dppm = bis(diphenylphosphino)methane, Ph2PCH2PPh2] to cis,cis-[MnBr(CO)2{P(OPh)3}(dppm)] is catalysed by the manganese(II) cation trans-[MnBr(CO)2{P(OPh)3}(dppm)]+.Keywords
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