On the reductive amination of aldehydes and ketones catalyzed by homogeneous Rh(i) complexes
- 15 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1867-1868
- https://doi.org/10.1039/b005777k
Abstract
The homogeneously catalyzed reductive amination of aldehydes and ketones under smooth conditions is reported, showing for the first time, that Rh(I) catalysts based on chelating diphosphines and diphosphinites can be advantageously employed for this reaction, even for the production of chiral amino acid derivatives.Keywords
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