E.s.r. studies of some working haem analogues Mn(PR3)X2 and their dioxygen adducts
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 68-70
- https://doi.org/10.1039/c39820000068
Abstract
The reversible dioxygenation of Mn(PR3)X2(R = n-butyl, n-pentyl, X = Cl, Br, I) has been studied in solution by e.s.r. spectroscopy; the dioxygenated species, ‘Mn(PR3)(O2)X2,’ have the highly unusual spin state S= 5/2.Keywords
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