Nitrogen-containing carbohydrate derivatives. Part XXVII. Synthesis and reactions of 3-cyano-3-deoxy-glycose derivatives
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 658-662
- https://doi.org/10.1039/p19720000658
Abstract
Treatment of sugar oxirans with hydrogen cyanide–triethylaluminium in ether has been shown to be a useful method for the synthesis of cyano-deoxy-glycoses. Reactions of such compounds have been studied, in particular epimerisation at the cyanide-bearing centre, and formation of cyano-olefin derivatives.Keywords
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