The titanium(IV) complex of a hexadentate tricatechol ligand: synthesis, crystal structure and electrochemistry
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 224-225
- https://doi.org/10.1039/c39910000224
Abstract
The tricatechol ligand, tripace, forms an octahedral complex with TiIV; the complex possesses a protonated central nitrogen atom in the ‘in’ conformation and is stable towards reduction up to E1/2=–1.02 V vs. standard calomel electrode.Keywords
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