New Synthesis of Diethyl Auylphosphonates and Diethyl Alkenylphosphonates
- 1 July 1989
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 19 (11-12) , 1891-1898
- https://doi.org/10.1080/00397918908052580
Abstract
Organometallic reagents readily added to diethyl l-(trimethylsilyl) vinylphosphonate 1 by virtue of the polarizing silyl group. Quenching with acetic acid, methyl iodide, and carbonyl compounds gave synthetically useful diethyl alkylphosphonates 6 and diethyl alkenylphosphonates 8 respectively.Keywords
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