Thermal expansion of corundum structure Ti2O3 and V2O3

Abstract
The thermal expansion coefficients of the corundum structure oxides Ti2O3 and V2O3 were measured by elevated‐temperature x‐ray diffraction techniques, the former to 300 °C and the latter to 1000 °C. Compared with corundum, both of these oxides exhibit deviations in their thermal expansion behavior which may be attributed to electronic interactions of the transition metal cations.

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