Abstract
The preparation of the fluorophosphines, ButPF2 and But 2PF, and of the fluorophosphoranes, But nPF5–n(n= 1–3) as well as of the related oxygen and sulphur compounds, But nP(:X)F3–n(n= 1 or 2; X = O or S), is described, 1H, 19F, and 31P N.m.r. data for these compounds are reported and discussed.

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