Reaction of (PPh3)2ReH7with dienes: preparation and some properties of trihydrido η4-diene and dihydro η5-dienyl complexes of rhenium

Abstract
The title compound reacts with dienes to give trihydrido η4-diene or dihydrido η5-dienyl complexes; pyrolysis of the η5-cyclohexadienyl compound (6) gives the hydrido arene complex (7), and protonation of the η4-diene compounds (4) leads to complete hydrogenation of the dienes.

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