THE ABSTRACTION OF HYDROGEN ATOMS FROM AMINES AND RELATED COMPOUNDS
- 1 August 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (8) , 1339-1345
- https://doi.org/10.1139/v60-188
Abstract
The reaction of methyl radicals with a group of amines and amine-like compounds has been investigated in the temperature range 125° to 157 °C. The abstraction activation energies of hydrogen atoms from these compounds, the corresponding pre-exponential factors, and the actual reaction rates indicate that the N—H hydrogen atoms are more labile than the C—H atoms in these compounds.Keywords
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