Linear correlation between entropies of complexation of cryptand 222 with metal ions in non-aqueous solvents and entropies of solvation of these ions in these solvents
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 84 (7) , 2441-2444
- https://doi.org/10.1039/f19888402441
Abstract
A linear correlation between entropies of complexation of cryptand 222 with alkali-metal and silver cations in non-aqueous solvents and entropies of solvation of these ions in these solvents is shown. This correlation can be used for the evaluation of entropies for the transfer of alkali-metal and silver cations from water to non-aqueous solvents from data for entropies of complexation of alkali-metal and silver cryptates in the appropriate solvents or vice versa.Keywords
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