Heterocyclische Siebenring-Verbindungen, XXIII [1] Synthese und Thermolyseverhalten von 2-Methyl-4-phenyl-l-benzothiepinen / Heterocyclic Seven-Membered Ring Compounds, XXIII [1] Synthesisand Thermolytic Behaviourof 2-Methyl-4-phenyl-1-benzothiepins
Open Access
- 1 August 1979
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (8) , 1145-1148
- https://doi.org/10.1515/znb-1979-0821
Abstract
The anions derived from the seven-membered 2-methyl-diketone (3) and the enolether (4) were alkylated resp. acylated to the 2-methyl-4-phenyl-l-benzothiepins (6), (7) resp. (8). Compound 4 could also be obtained by C-methylation of the enolether (2). The thermal decomposition of the 2-methyl-4-phenyl-l-benzothiepins yielded exclusively sulphur and the corresponding I-methyl-3-phenyl-naphthalenes (9), (10) resp. (11).Keywords
This publication has 0 references indexed in Scilit: